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A total of 21 world leaders, including Vladimir Putin, Angela Merkel and Prince Albert of Monaco, have already confirmed they will travel to Brazil for the World Cup.
Brazilian President Dilma Rousseff's office said UN Secretary-General Ban Ki-moon and 11 heads of state and government would attend the opening match between Brazil and Croatia on June 12 in Sao Paulo.
Among the guests will be the Emir of Qatar Tamim Bin Hamad Al Thani, Gabonese President Ali Bongo Ondimba and Bolivia's Evo Morales.
Russia's President Putin, whose country will host the next World Cup in 2018, has already announced that he will attend the final match set for July 13 at Maracana Stadium in Rio de Janeiro.
Others, including German Chancellor Merkel and US Vice President Joe Biden, will watch one or two match ups and will hold bilateral talks on the sidelines with Rousseff.
Here is the list released by Rousseff's office:
German Chancellor Angela Merkel - Germany-Portugal match, Salvador, June 16
Belgium's King Philippe and Queen Mathilde, and Prime Minister Elio Di Rupo - Belgium-Russia match, Rio de Janeiro, June 22
Chilean President Michelle Bachelet - opening match in Sao Paulo on June 12 and Chile-Australia match in Cuiaba, June 13
Croatian Prime Minister Zoran Milanovic - Brazil-Croatia opening match and Croatia-Cameroon match, Manaus, June 18
Ecuadoran President Rafael Correa - opening match
US Vice President Joe Biden - US-Ghana match, Natal, June 16
Ghana President John Mahama - opening match
Honduran President Juan Orlando Hernandez - Honduras-France match, Porto Alegre, June 16
King Willem-Alexander of the Netherlands - Netherlands-Australia match, Porto Alegre, June 18
Russian President Vladimir Putin - final match, Rio de Janeiro, July 13
Uruguay's President Jose Mujica - opening match
Prince Albert II of Monaco - Argentina-Bosnia match, Rio de Janeiro, June 15 and South Korea-Belgium, Sao Paulo, June 26
Emir of Qatar Tamim bin Hamad Al Thani - opening match
Suriname President Desire Bouterse - opening match
Angola President Jose Eduardo dos Santos - opening match
Bolivian President Evo Morales - opening match
Gabonese President Ali Bongo Ondimba - opening match
Paraguayan President Horacio Cartes - opening match
Kenyan President Uhuru Kenyatta - semi final, location unknown, and final
UN Secretary-General Ban Ki-moon - opening match
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