The envoy had only met the woman a few times, during which she had hidden her face behind a niqab, or face-covering veil, the paper said.
After the marriage contract was signed, the ambassador attempted to kiss his bride-to-be, upon which he discovered she had facial hair and was cross-eyed, it said.
The ambassador told an Islamic Sharia court in the United Arab Emirates that he was tricked into the marriage as the woman's mother had shown his own mother pictures of her sister instead of her, the report said.
He sued for the contract to be annulled and also demanded the woman pay him Dh500,000 ($136,000) for clothes, jewelry and other gifts he had bought for her.
The court annulled the contract but rejected the ambassador's demand for compensation.
The report did not identify the ambassador nor give any further details.